Levels of chlorinated hydrocarbons and trace metals in bivalves and nearshore sediments from the Dominican Republic     

Luciano Sbriz  Margarita R. Aquino  Natividad M. Alberto de rodriguez  Scott W. Fowler  Jose L. Sericano 《Marine pollution bulletin》1998,36(12):971-979

Bivalves (Crassostrea rizhophorae, Isognomon alatus, Codakia orbicularis Linné, and Tellina fausta) and sediment samples collected from 12 locations along the Dominican Republic coastline were used to assess the degree of nearshore contamination by selected chlorinated hydrocarbons and heavy metals. Concentrations of total chlordanes, DDTs and PCBs ranged from 0.51 to 7.47 ng/g, < MDL to 30.9 ng/g and 11.3 to 82.3 ng/g, and from < MDL to 1.73 ng/g, 0.21 to 12.5 ng/g and 0.46 to 41.9 ng/g in bivalves and surface sediments, respectively. The concentration ranges of predominantly anthropogenic Cu, Pb and Zn were 3.08–866 μg/g, 0.08–1.46 μg/g and 22.9–4380 μg/g in bivalve soft parts and 1.01–111 mg/g, 0.420–134 μg/g and 1.96–277 μg/g in surface sediments, respectively. Mercury concentrations ranged from 0.290 to 7.02 μg/g and from 0.096 to 0.565 μg/g in both matrices. The relatively high Hg concentrations found in bivalves from two stations in Bahia Samana, near to a known source of past Hg contamination in the sediments, require a more in-depth survey of the area. In general the concentrations of selected chlorinated hydrocarbons and trace metals, compared with those reported for the same matrices in the Caribbean and west Atlantic coastal areas, show at present the existence of only very localized contamination problems in the Dominican Republic.  相似文献   

Analyticity, scaling and renormalization for some complex analytic dynamical systems     

Alberto Berretti 《Planetary and Space Science》1998,46(11-12)

We review some results about the analytic structure of Lindstedt series for some complex analytic dynamical systems: in particular, we consider Hamiltonian maps (like the standard map and its generalizations), the semi-standard map and Siegel's problem of the linearization of germs of holomorphic diffeomorphisms of ( ,0). The analytic structure of those series can be studied numerically using Padé approximants, and one can show the existence of natural boundaries for real, diophantine values of the rotation number; by complexifying the rotation number, we show how these natural boundaries arise from the accumulation of singularities due to resonances, providing a new intuitive insight into the mechanism of the break-down of invariant KAM curves. Moreover, we study the Lindstedt series at resonances, i.e. for rational values of the rotation number, by suitably rescaling to 0 the value of the perturbative parameter, and a simple analytic structure emerges. Finally, we present some proofs for the simplest models and relate these results to renormalization ideas.  相似文献   

Origin of peraluminous granites and granodiorites, Iberian massif, Spain: an experimental test of granite petrogenesis   总被引：27，自引：0，他引：27  

Antonio Castro  Alberto E. Patiño Douce  L. Guillermo Corretgé  Jesús D. de la Rosa  Mohammed El-Biad  Hassan El-Hmidi 《Contributions to Mineralogy and Petrology》1999,135(2-3):255-276

The discrimination between potential source materials involved in the genesis of Iberian granites and granodiorites, as well as the role of mantle-crust interactions, are examined using constraints imposed by melting experiments, melting-assimilation experiments and Sr-Nd isotope systematics. The Sr-Nd isotope relationships indicate the existence of different genetic trends in which juvenile mantle materials are involved by different mechanisms: (1) a source trend, traced by a particular evolution of the pre-Hercynian basement and indicating mantle participation at the time of sedimentation; (2) a set of magmatic trends traced by gabbro-tonalite-enclave-granodiorite associations, implying the incorporation of new mantle material at the time of granite generation. These relationships strongly support a pure crustal origin for the peraluminous leucogranites, derived from partial melting of crustal protoliths, and a hybrid origin for the peraluminous granodiorites. These granodiorites are the most abundant granitic rocks of the Central Iberian zone (CIZ) of the Iberian massif, implying that processes of hybridisation by assimilation and/or magma mixing played an important role in granitoid production during the Hercynian orogeny. These hypotheses have been tested by means of melting and assimilation experiments. Melting experiments in the range 800–900 °C and at pressures of 3, 6, 10 and 15 kbar indicate that: (1) several potential source materials such as Bt-Ms gneisses and metagreywackes are suitable for the production of peraluminous leucogranite melts; (2) the melt compositions are always leucogranitic, regardless of pressure; (3) pressure exerts a strong influence on the fertility of the source: experiments at 3 kbar produce more than 20 vol% of melt, compared with less than 5 vol% of melt produced at 10 and 15 kbar and at the same temperature. The melting-assimilation experiments carried out at 1000 °C and 4, 7 and 10 kbar and using a proportion of 50% gabbro and 50% gneiss give high melt proportions (more than 50 vol.%) and noritic residues. These melts have the composition of leucogranodiorites, and overlap with part of the compositional range of peraluminous granodiorites of the Iberian massif. The generation of more mafic granodiorites may be explained by the incorporation of some residual orthopyroxene to the granodiorite magmas. The low solubility of Fe + Mg prevents the generation of granodiorite melts with more than 3 wt% of MgO + FeO at all crustal pressures. The large volumes of peraluminous, hybrid granodiorites, produced by assimilation of crustal rocks by mantle magmas, imply that an important episode of crustal growth took place during the Late-Palaeozoic Hercynian orogeny in the Iberian massif. Received: 30 June 1998 / Accepted: 27 November 1998  相似文献   

Taphonomy of guanaco bones in Tierra del Fuego     

Luis Alberto Borrero 《Quaternary Research》1990,34(3)

Guanaco carcasses are deposited in great quantities in Cabo San Pablo, Tierra del Fuego (Argentina), as a result of winter stress. Taphonomic studies indicate that the gnawing action of foxes on guanaco (Lama guanicoe) carcasses produces only very tenuous marks on the bones. Lack of sustained interest in the carcasses by carnivores results in slow disarticulation. The articulated and disarticulated bones are exposed to heavy trampling by guanacos, a process that produces vertical migration of small/dense bones and fracturing of the most weathered bones. An understanding of this ongoing process is important for local archaeology, since modern bones are migrating into archaeological contexts. A regional approach to taphonomy is the most appropriate instrument to solve this and other related problems.  相似文献   

U–Pb evidence for a polyorogenic evolution of the HP–HT units of the NW Iberian Massif     

Javier Fernández-Suárez  Fernando Corfu  Ricardo Arenas  Alberto Marcos  José R. Martínez Catalán  Florentino García  Jacobo Abati  Francisco J. Fernández 《Contributions to Mineralogy and Petrology》2002,143(2):236-253

. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.  相似文献   

Spatial and temporal variation of the nekton and hyperbenthos from a temperate European estuary with regulated freshwater inflow     

Pilar Drake  Alberto M. Arias  Francisco Baldó  José A. Cuesta  Antonio Rodríguez  Alfonso Silva-Garcia  Ignacio Sobrino  Diego García-González  Carlos Fernández-Delgado 《Estuaries and Coasts》2002,25(3):451-468

The aquatic macrofauna of the Guadalquivir estuary were sampled (1 mm mesh persiana net) at 5 sampling sites located along the entire (except the tidal freshwater region) estuarine gradient of salinity (outer 50 km). A total of 134 fish and macroinvertebrate species was collected but only 62 were considered common or regularly present in the estuary. Univariate measures of the community structure showed statistically significant differences among sampling sites: species richness, abundance, and biomass decreased in the upstream direction, being positively correlated with the salinity. Temporal differences of these three variables were also statistically significant. While a clear seasonal pattern (minimum densities in winter and maximum in spring-summer) was observed for abundance and biomass, no such pattern existed for the number of species. Mysids was the most dominant group throughout the estuary (96% to 99% of abundance; 49% to 85% of biomass), although fish biomass was also important at the outer estuary (36% to 38%). Multivariate analyses indicated highly significant spatial variation in the macrofaunal communities observed along the salinity gradient. These analyses suggest that the underlying structure was a continuum with more or less overlapping distributions of the species dependent on their ability to tolerate different physicochemical conditions. There were also significant temporal (intermonthly + interannual) variation of the estuarine community; the relative multivariate dispersion indicated that monthly variation was more considerable (relative multivariate dispersion >1) at the outer part of the estuary during the wet year (last 20 km) and was higher in the inner stations during the dry year (32 to 50 km from the river mouth). Since a clear negative exponential relationship was observed between the freshwater input (from a dam located 110 km upstream) and water salinity at all sampling stations, it is concluded that the human freshwater management is probably affecting the studied estuarine communities. While the higher seasonal (long-term) stability of the salinity gradient, due to the human control of the freshwater input, may facilitate the recruitment of marine species juveniles during the meteorologically unstable early-spring, the additional (short-term) salinity fluctuations during the warm period may negatively affect species that complete their lifecycle within the estuary.  相似文献   

Internal structure and kinematics of Variscan thrust sheets in the valley of the Trubia River (Cantabrian Zone, NW Spain): regional tectonic implications     

Mayte Bulnes  Alberto Marcos 《International Journal of Earth Sciences》2001,90(2):287-303

The Variscan Belt in western Europe shows an arcuate geometry that is usually named Ibero-Armorican Arc. The nucleus of this arc, known as the Asturian Arc, comprises the Cantabrian Zone which is a foreland fold and thrust belt. The Trubia River area is located in the inflexion zone of the Asturian Arc, which is a strategic structural position for unraveling the geometry and kinematics of the Variscan thrust sheets and related folds. Geological mapping, construction of stratigraphic and structural cross sections, analysis of kinematic indicators, and estimate of shortening for each cross section have been carried out. This area consists of two major antiform-synform pairs related to two imbricate thrust systems. These folds are asymmetric, tight, and their axial traces follow the trend of the Asturian Arc. They have been interpreted as fault-propagation folds. The emplacement directions measured in the Trubia River area change from north to south and converge towards the core of the Asturian Arc. The minimum shortening estimated ranges between 16.4 and 17.6 km, which corresponds to 56.9 and 59.4%. The complex cross-cutting relationships between folds and thrusts suggest that, in general, the different structural units followed a forward-breaking sequence of emplacement, with some breaching and a few out-of-sequence thrusts. The analysis of the transport vectors together with the disposition of the fold axes and post-thrusting faults that deform the thrust stack are evidence of a late deformation event that is partially or totally responsible for the arcuate form of the Asturian Arc. The timing of the Asturian Arc, amount of shortening, and sequence of emplacement of the structures are in accordance with previous regional studies of the Cantabrian Zone.  相似文献   

Natural and anthropogenic C2 to C6 hydrocarbons in the central-eastern Venezuelan atmosphere during the rainy season     

Loreto Donoso  Rodrigo Romero  Alberto Rondón  Emmanuel Fernandez  Pedro Oyola  Eugenio Sanhueza 《Journal of Atmospheric Chemistry》1996,25(2):201-214

The levels of low molecular weight hydrocarbons were measured at pristine sites and rural locations affected by hydrocarbon emissions from oil and gas producing fields in Venezuela. At the clean sites, lower concentrations of C₂ to C₆ alkanes were observed, whereas, in comparison with remotes sites, very much higher levels were measured at the polluted sites. Alkenes present relatively high concentrations, with isoprene being the most abundant, all over the study region. The main sources of alkenes are likely to be natural, mainly from vegetation. The levels of alkanes recorded at the clean sites and the alkene levels found everywhere in the region are in agreement with the values reported for other clean sites in the tropics. The increase of ozone production capacity due to the anthropogenic emissions of alkanes from oil and gas fields was estimated. Due to the presence in the atmosphere of important amounts of naturally emitted isoprene, ethene and propene, which makes a substantial contribution to the reactivity of the hydrocarbon mixture, a small increase (<5%) was estimated to occur in the capacity of the ozone production at a regional scale during the rainy season.  相似文献   

Soil-structure interaction with Rayleigh waves     

Alberto Gmez-Mass  John Lysmer  Jian-Chu Chen  H. Bolton Seed 《地震工程与结构动力学》1983,11(4):567-583

Presented is a plane-strain method for soil-structure interaction analysis consisting of the superposition of the free field motions and the interaction motions in a generalized seismic environment. The free field is modelled as a horizontally layered viscoelastic medium and the seismic environment may consist of a combination of S, P and Rayleigh waves. The soil-structure system is modelled with viscoelastic finite elements, transmitting boundaries, viscous boundaries and a three-dimensional simulation. Comparative analyses of the same structure are conducted for an input of R waves and for vertically propagating S and P waves in a rock site and sand site. In the rock site the R waves produce higher peak horizontal spectral acceleration up to 25 per cent, and a significant rocking effect at points away from the centre of gravity of the structure. However, the S and P waves show higher peak vertical spectral acceleration by up to 15 per cent at the centre of the structure. Very similar horizontal response, but higher vertical response only at the centre of the structure for S and P waves, is obtained for the sand site.  相似文献   

Asteroid “clans”: Super-families or multiple events?     

Alberto Cellino  Vincenzo Zappalà 《Celestial Mechanics and Dynamical Astronomy》1993,57(1-2):37-47

Among the recently determined asteroid families (Zappala' et al., 1992) a number of very large clusterings are recognized. Some of them agglomerate few families previously identified as single groupings. In most cases, the new big families (called clans) seem to be composed by different sub-clusterings connected each other by very narrow bridges. In the present paper we analyze their possible origin and evolution: a primordial single event followed by subsequent collisions of the fragments, a super-catastrophic original impact or different collisional events overlapping by chance.  相似文献